A team of researchers has created a new class of titanium alloys that are strong and not brittle under tension, by inte­grating alloy and 3D-printing process designs. The apporach could help extend the applications of titanium alloys, improve sustainability and drive innovative alloy design. Their discovery holds promise for a new class of more sustainable high-perfor­mance titanium alloys for applications in aerospace, biomedical, chemical engineering, space and energy technologies. RMIT University and the University of Sydney led the inno­vation, in colla­boration with Hong Kong Polytechnic University and the company Hexagon Manu­facturing Intelligence in Melbourne.

Lead researcher Ma Qian from RMIT said the team embedded circular economy thinking in their design, creating great promise for producing their new titanium alloys from industrial waste and low-grade materials. “Reusing waste and low-quality materials has the potential to add economic value and reduce the high carbon footprint of the titanium industry,” said Qian from the Center for Additive Manu­facturing in the School of Engineering. The team’s titanium alloys consist of a mixture of two forms of titanium crystals alpha-titanium phase and beta-titanium phase, each corresponding to a specific arrangement of atoms. This class of alloys has been the backbone of the titanium industry. Since 1954, these alloys have been produced primarily by adding aluminum and vanadium to titanium.

The research team inves­tigated the use of oxygen and iron – two of the most powerful stabi­lizers and strengtheners of alpha- and beta-titanium phases – which are abundant and inexpensive. Two challenges have hindered the development of strong and ductile alpha-beta titanium-oxygen-iron alloys through the conventional manu­facturing processes, Qian said. “One challenge is that oxygen – described collo­quially as the kryptonite to titanium – can make titanium brittle, and the other is that adding iron could lead to serious defects in the form of large patches of beta-titanium.”

The team used Laser Directed Energy Deposition (L-DED), a 3D printing process suitable for making large, complex parts, to print their alloys from metal powder. “A key enabler for us was the combi­nation of our alloy design concepts with 3D-printing process design, which has identified a range of alloys that are strong, ductile and easy to print,” Qian said. The attractive properties of these new alloys that can rival those of commercial alloys are attributed to their microstructure, the team says. “This research delivers a new titanium alloy system capable of a wide and tunable range of mechanical properties, high manu­facturability, enormous potential for emissions reduction and insights for materials design in kindred systems,” said Simon Ringer from University of Sydney.

“The critical enabler is the unique distribution of oxygen and iron atoms within and between the alpha-titanium and beta-titanium phases. We've engineered a nanoscale gradient of oxygen in the alpha-titanium phase, featuring high-oxygen segments that are strong, and low-oxygen segments that are ductile allowing us to exert control over the local atomic bonding and so mitigate the potential for embrittlement”, Ringer said. Tingting Song from RMIT added the team is “at the start of a major journey, from the proof of our new concepts here, towards industrial appli­cations. There are grounds to be excited – 3D printing offers a funda­mentally different way of making novel alloys and has distinct advantages over traditional approaches.”

“There’s a potential opportunity for industry to reuse waste sponge titanium-oxygen-iron alloy, out-of-spec recycled high-oxygen titanium powders or titanium powders made from high-oxygen scrap titanium using our approach,” she said. Zibin Chen, who joined Hong Kong Polytechnic University from the University of Sydney in the later stages of the colla­boration, said the research had broader implications. “Oxygen embrittlement is a major metallur­gical challenge not only for titanium, but also for other important metals such as zirconium, niobium and molybdenum and their alloys,” he said. “Our work may provide a template to mitigate these oxygen embrittlement issues through 3D printing and micro­structure design.” (Source: RMIT)

Reference: T. Song et al.: Strong and ductile titanium–oxygen–iron alloys by additive manufacturing, Nature 618, 63 (2023); DOI: 10.1038/s41586-023-05952-6

Link: Centre for Additive Manufacturing, School of Engineering, RMIT University, Melbourne, Australia